| Rank | Name | Team | Red Cards | Yellow Cards | Total Cards |
| 1 | Maurizio Lanzaro | Zaragoza | 3 | 13 | 16 |
| 2 | Javier Martinez | Athletic Bilbao | 3 | 13 | 16 |
| 3 | Mario Alvarez | Betis | 3 | 6 | 9 |
| 4 | Juan Forlín | Espanyol | 2 | 14 | 16 |
| 5 | Pape Kouli Diop | Santander | 2 | 13 | 15 |
| 6 | Juanfran Garcia | Levante | 2 | 12 | 14 |
| 7 | Ivan Ramis | Mallorca | 2 | 11 | 13 |
| 8 | Fernando Amorebieta | Athletic Bilbao | 2 | 11 | 13 |
| 9 | Inigo Martinez | Real Sociedad | 2 | 9 | 11 |
| 10 | Daniel Alves | Barcelona | 2 | 8 | 10 |
| 11 | Alberto Ramos Lora | Gijon | 2 | 7 | 9 |
| 12 | Isco | Malaga | 2 | 7 | 9 |
| 13 | Alberto Lopo | Getafe | 2 | 6 | 8 |
| 14 | Roland Lamah | Osasuna | 2 | 6 | 8 |
| 15 | Guilherme Siqueira | Granada | 2 | 6 | 8 |
| 16 | Gorka Elustondo | Real Sociedad | 2 | 5 | 7 |
| 17 | Eneko Satrustegui | Osasuna | 2 | 5 | 7 |
| 18 | Jaime Romero | Granada | 2 | 3 | 5 |
| 19 | Jose Manuel Casado | Rayo Vallecano | 1 | 17 | 18 |
| 20 | Gary Medel | Sevilla | 1 | 16 | 17 |
| 21 | Gabi Fernández | Atletico Madrid | 1 | 13 | 14 |
| 22 | Jordi Alba | Valencia | 1 | 13 | 14 |
| 23 | Sergio Ramos | Real Madrid | 1 | 12 | 13 |
| 24 | Fernando Navarro | Sevilla | 1 | 12 | 13 |
| 25 | Tino Costa | Valencia | 1 | 12 | 13 |
| 26 | Paxti Martinez Punal | Osasuna | 1 | 11 | 12 |
| 27 | Michel | Getafe | 1 | 11 | 12 |
| 28 | Javi Lopez | Espanyol | 1 | 11 | 12 |
| 29 | Pepe | Real Madrid | 1 | 10 | 11 |
| 30 | David Albelda | Valencia | 1 | 10 | 11 |
| 31 | Raul Garcia | Atletico Madrid | 1 | 10 | 11 |
| 32 | Miranda | Atletico Madrid | 1 | 10 | 11 |
| 33 | Vicente de La Fuente Iborra | Levante | 1 | 10 | 11 |
| 34 | Dani Benitez | Granada | 1 | 10 | 11 |
| 35 | Miguel Torres | Getafe | 1 | 9 | 10 |
| 36 | Domingo Cisma | Santander | 1 | 9 | 10 |
| 37 | Michu | Rayo Vallecano | 1 | 9 | 10 |
| 38 | Oscar De Marcos | Athletic Bilbao | 1 | 9 | 10 |
| 39 | Andoni Iraola | Athletic Bilbao | 1 | 8 | 9 |
| 40 | Mikel González | Real Sociedad | 1 | 8 | 9 |
| 41 | Julien Escudé | Sevilla | 1 | 8 | 9 |
| 42 | Piotr Trochowski | Sevilla | 1 | 8 | 9 |
| 43 | Sofiane Feghouli | Valencia | 1 | 8 | 9 |
| 44 | Ruben Micael | Zaragoza | 1 | 8 | 9 |
| 45 | Pedro Botelho | Levante | 1 | 8 | 9 |
| 46 | Martin Demichelis | Malaga | 1 | 7 | 8 |
| 47 | Carlos Marchena | Villarreal | 1 | 7 | 8 |
| 48 | Frédéric Kanouté | Sevilla | 1 | 7 | 8 |
| 49 | Pedro Munitis | Santander | 1 | 7 | 8 |
| 50 | Gerard Piqué | Barcelona | 1 | 7 | 8 |
| 51 | Sebastian Eguren | Gijon | 1 | 7 | 8 |
| 52 | Jérémy Toulalan | Malaga | 1 | 7 | 8 |
| 53 | Diego Godin | Atletico Madrid | 1 | 7 | 8 |
| 54 | Federico Fazio | Sevilla | 1 | 7 | 8 |
| 55 | Pablo Sebastian Alvarez | Zaragoza | 1 | 6 | 7 |
| 56 | Mehdi Lacen | Getafe | 1 | 6 | 7 |
| 57 | Angel Di Maria | Real Madrid | 1 | 6 | 7 |
| 58 | Roberto Canella | Gijon | 1 | 6 | 7 |
| 59 | Jose Dorado | Betis | 1 | 5 | 6 |
| 60 | Hurtado Perez Moisés | Granada | 1 | 5 | 6 |
| 61 | Aritz Aduriz | Valencia | 1 | 5 | 6 |
| 62 | Mesut Özil | Real Madrid | 1 | 5 | 6 |
| 63 | Manu Del Moral | Sevilla | 1 | 5 | 6 |
| 64 | Carlos Martins | Granada | 1 | 5 | 6 |
| 65 | Tono | Santander | 1 | 5 | 6 |
| 66 | Gonzalez Carmelo | Gijon | 1 | 5 | 6 |
| 67 | Jesus Perez Francis | Santander | 1 | 5 | 6 |
| 68 | Abdelaziz Barrada | Getafe | 1 | 5 | 6 |
| 69 | Joan Oriol | Villarreal | 1 | 5 | 6 |
| 70 | Franco Zuculini | Zaragoza | 1 | 5 | 6 |